Presidential Young Investigator Award: Chemical Dynamics of Rovibrationally Excited Molecules

总统青年研究员奖：旋转激发分子的化学动力学

• 批准号: 9158107
• 负责人: Patrick Vaccaro
• 金额: $ 31.25万
• 依托单位: Yale University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1991
• 资助国家: 美国
• 起止时间: 1991-08-01 至 1997-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9158107&HistoricalAwards=false
• 关键词: Presidential; Young; Investigator; Award; Chemical

In this project in the Experimental Physical Chemistry Program of the Chemistry Division, Vaccaro will study the spectroscopy, relaxation, and chemical reactivity of rovibrationally excited polyatomic molecules as a function of both the magnitude and type of excitation of the molecular framework. The first state-to-state measurements of polyatomic reaction dynamics will be performed. Novel multiple-resonance laser techniques will be used to prepare molecules in specific rotation-vibration states. %%% Studies of the reactivity of polyatomic molecules which contain chemically significant quantities of energy of excitation are important because of the information they can reveal about aeronomic and combustion-related processes. On a fundamental scientific level, these transient species can reveal much regarding the nature and origin of such phenomena as mode- or bond-specific chemistry and quantum chaos.

在化学部实验物理化学项目的这个项目中，瓦卡罗将研究振动激发多原子分子的光谱、弛豫和化学反应性，作为分子框架激发强度和类型的函数。 将进行多原子反应动力学的首次状态到状态测量。 新型多共振激光技术将用于制备特定旋转振动状态的分子。 %%% 对含有化学上大量激发能量的多原子分子的反应性的研究很重要，因为它们可以揭示有关航空和燃烧相关过程的信息。 在基础科学层面上，这些瞬态物质可以揭示许多有关模式或键特定化学和量子混沌等现象的性质和起源的信息。